Studies on Green Synthetic Reactions Based on Formic Acid from Biomass
Produktnummer:
18fe44b244b013488ab8ad5551dd27ebc7
| Autor: | Fu, Ming-Chen |
|---|---|
| Themengebiete: | Carbon monoxide Carbonylation Formic Acid Hydrocarboxylation Methylation Unsaturated Carboxylic Acids |
| Veröffentlichungsdatum: | 11.08.2020 |
| EAN: | 9789811576225 |
| Sprache: | Englisch |
| Seitenzahl: | 105 |
| Produktart: | Gebunden |
| Verlag: | Springer Singapore |
Produktinformationen "Studies on Green Synthetic Reactions Based on Formic Acid from Biomass"
This book introduces readers to the use of formic acid for efficient organic synthesis. It describes the N-methylation of aromatic and aliphatic amines with formic acid using a boron-based catalyst [B(C6F5)3] in combination with silanes and without the need for an expensive transition metal catalyst. It also shows that formic acid interacts with alkynes and allyl alcohols through a carbonylation process that generates carbon monoxide in situ from nickel and palladium catalysis, respectively, doing away with the need to use high-pressure CO gas and offering a user-friendly and practical method for preparing functionalized a, ß- and ß, ?-unsaturated carboxylic acids. The findings presented not only enrich the field of ‘C1 chemistry,’ but also support the advancement of green and sustainable chemistry.
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