On the Catalytic Efficacy of Low-Oxidation State Group 14 Complexes
Produktnummer:
18b53887e8361b4b49b0a476a01a0462be
| Autor: | Hadlington, Terrance John |
|---|---|
| Themengebiete: | CO2 Reduction Catalysis Group 14 Catalysis Heavier Tetrylenes Hydrogen Activation Main Group Chemistry Oxidative Addition Small-molecule Activation |
| Veröffentlichungsdatum: | 27.02.2017 |
| EAN: | 9783319518060 |
| Sprache: | Englisch |
| Seitenzahl: | 243 |
| Produktart: | Gebunden |
| Verlag: | Springer International Publishing |
Produktinformationen "On the Catalytic Efficacy of Low-Oxidation State Group 14 Complexes"
This outstanding thesis describes a detailed investigation into the use of low-oxidation-state group 14 complexes in catalysis, developed at the cutting edge of inorganic and organometallic chemistry. It includes the preparation of a number of landmark compounds, some of which challenge our current understanding of metal–metal bonding and low-oxidation-state main group chemistry. Among the many highlights of this thesis, the standout result is the development of the first well-defined, low- oxidation-state main group hydride systems as highly efficient catalysts in the hydroboration of carbonyl substrates, including carbon dioxide, which are as efficient as those observed in more traditional, transition-metal catalyses. These results essentially define a new subdiscipline of chemistry.
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